Water Can Accelerate Homogeneous Gold Catalysis

Homogeneous Catalysis Homogeneous Catalysis

Fe b 20 09 Homogeneous Gold Catalysis through Relativistic Effects : Addition of Water to Propyne . ∗

This work was supported by the Royal Society of New Zealand through a Marsden grant. We acknowledge the use of extensive computer time on Massey University’s parallel supercomputer facilities Doublehelix and Bestgrid. Dr. Matthias Lein, Prof. Dr. Peter Schwerdtfeger, Center for Theoretical Chemistry and Physics, New Zealand Institute for Advanced Study, Massey University Auckland, Private Bag 1...

Homogeneous Gold Catalysis through Relativistic Effects : Addition of Water to Propyne . ∗

This work was supported by the Royal Society of New Zealand through a Marsden grant. We acknowledge the use of extensive computer time on Massey University’s parallel supercomputer facilities Doublehelix and Bestgrid. Dr. Matthias Lein, Prof. Dr. Peter Schwerdtfeger, Center for Theoretical Chemistry and Physics, The New Zealand Institute for Advanced Study, Massey University Auckland, Private B...

A conceptual translation of homogeneous catalysis into heterogeneous catalysis: homogeneous-like heterogeneous gold nanoparticle catalyst induced by ceria supporter.

Translation of homogeneous catalysis into heterogeneous catalysis is a promising solution to green and sustainable development in chemical industry. For this purpose, noble metal nanoparticles represent a new frontier in catalytic transformations. Many challenges remain for researchers to transform noble metal nanoparticles of heterogeneous catalytic active sites into ionic species of homogeneo...

Combining Zn Ion Catalysis with Homogeneous Gold Catalysis: An Efficient Annulation Approach to N-Protected Indoles.

The Fischer indole synthesis is perhaps the most powerful method for indole preparation, but it often suffers from low regioselectivities with unsymmetric aliphatic ketone substrates and strong acidic conditions and is not suitable for α,β-unsaturated ketones. In this article, we disclose an efficient synthesis of N-protected indoles from N-arylhydroxamic acids/N-aryl-N-hydroxycarbamates and a ...